We present high spectral resolution and high-sensitivity observations
of the J = 1 --> 0 transition of N2H+ at 93 GHz toward the quiescent l
ow-mass cloud core L1512 in Taurus. The relative frequencies of the se
ven hyperfine components of this transition have been determined with
precision similar to 1 kHz, and the absolute frequencies with precisio
n similar to 7 kHz The hyperfine coupling constants have been determin
ed with precision an order of magnitude higher than previously in the
laboratory. Relative intensities of the hyperfine components of N2H+ i
n L1512 as well as in a sample of similar to 60 low-mass cloud cores a
re not consistent with a single excitation temperature model fit, indi
cating the presence of excitation anomalies.