NMR INVESTIGATION OF THE POLYSILANE-POLYCARBOSILANE TRANSFORMATION OFPOLY(METHYLCHLOROSILANES)

Authors
BABONNEAU F RICHTER R BONHOMME C MAQUET J ROEWER G
Citation
F. Babonneau et al., NMR INVESTIGATION OF THE POLYSILANE-POLYCARBOSILANE TRANSFORMATION OFPOLY(METHYLCHLOROSILANES), Journal de chimie physique et de physico-chimie biologique, 92(10), 1995, pp. 1745-1748
Citations number
11
Categorie Soggetti
Biology,"Chemistry Physical
Journal title
Journal de chimie physique et de physico-chimie biologique → ACNP
Volume
92
Issue
10
Year of publication
1995
Pages
1745 - 1748
Database
ISI
SICI code
Abstract
The pyrolysis of poly(methylchlorosilanes) prepared by catalytic dispr oportionation of disilanes leads to the formation of silicon carbide. The first step of the process is a polysilane to polycarbosilane trans formation, which occurs with the insertion of methylene groups into Si -Si bonds. For the first time, this transformation was studied by C-13 MAS-NMR, using cross polarization (CP) and Inversion Recovery Cross P olarization (IRCP) techniques.