La. Pinnaduwage et al., ENHANCED NEGATIVE-ION FORMATION IN ARF-LASER IRRADIATED METHANE - POSSIBLE IMPLICATIONS FOR PLASMA PROCESSING DISCHARGES, Contributions to Plasma Physics, 35(4-5), 1995, pp. 433-438
Oberservation of enhanced electron attachment to ArF-excimer-laser irr
adiated methane is reported. Preliminary evidence is presented that la
ser-excited superexcited stares of CH4 (or other excited states to whi
ch these convert) are responsible for the observed enhanced electron a
ttachment, and, that predominantly H- ions are produced via this proce
ss. The possible significance of this process for plasma processing di
scharges using CH4 and its mixtures is indicated.