Rh. Hallett et al., AGGREGATION PHEROMONE OF COCONUT RHINOCEROS BEETLE, ORYCTES-RHINOCEROS (L) (COLEOPTERA, SCARABAEIDAE), Journal of chemical ecology, 21(10), 1995, pp. 1549-1570
Male coconut minoceros beetles, Oryctes rhinoceros (L.), produce three
sex-specific compounds, ethyl 4-methyloctanoate, ethyl 4-methylheptan
oate, and 4-methyloctanoic acid, the first of which is an aggregation
pheromone. Synthesis of these compounds involving conjugate addition o
f organocuprates to ethyl acrylate is reported. In field trapping expe
riments, (4S)-ethyl-4-methyloctanoate and the racemic mixture were equ
ally attractive and 10 times more effective in attracting beetles than
ethyl chrysanthemumate, a previously recommended attractant. Ethyl 4-
methylheptanoate was as attractive as ethyl chrysanthemumate and more
attractive than 4-methyloctanoic acid, but further studies are require
d before it can be classed as an aggregation pheromone. Compared to et
hyl 4-methyloctanoate alone, combinations of the three male-produced c
ompounds did not increase attraction, whereas addition of freshly rott
ing oil palm fruit bunches to pheromone-baited traps significantly enh
anced attraction. With increasing dose, captures of O. rhinoceros incr
eased, but doses of 6, 9, and 18 mg/day were competitive with 30 mg/da
y lures. Newly designed vane traps were more effective in capturing be
etles than were barrier or pitfall traps. Results of this study indica
te that there is potential for using ethyl 4-methyloctanoate in operat
ional programs to control O. rhinoceros in oil palm plantations.