We report the double resonance excitation of two pump waves with frequ
encies separated from 5 to several hundred Hz. The cyclotron frequenci
es of NO+ and O-2(+) abundant at the bottom of the F layer (similar to
150 km), are within this range. The nonlinear mode coupling takes pla
ce at similar to 150 km where the pump frequency matches the plasma fr
equency. The experiments show that when the beat frequency is close to
the NO+ cyclotron frequency at similar to 30 Hz, the energy transfer
from the higher frequency to the lower frequency wave is enhanced thro
ugh parametric coupling. When the two pump waves have equal power, dis
crete sidebands are symmetrically distributed around the pump frequenc
ies. However, a burst of lower-frequency sidebands, lasting for severa
l seconds, frequently breaks the symmetry. We attribute this asymmetry
to the cascade parametric process. The asymmetric spectra only occur
only during O mode experiments.