Phosphorous fertilizers of differing solubility (superphosphate, preci
pitate, and ground phosphate rock) had varying effects on the content
of phosphates extractable with 0.2 M HCl and on the content of the var
ious phosphate groups in a Sod-Podzolic soil. Superphosphate and preci
pitate applied to the soil were converted into soil aluminum phosphate
s, and to a lesser extent iron phosphates, as early as in the year of
application. When ground phosphate rock was applied, the content of mi
neral phosphates increased, mainly as calcium phosphates. These calciu
m phosphates were not really soil phosphates but rather fertilizer pho
sphates which had not reacted with the soil.