Aa. Kipriyanov et Ab. Doktorov, LONG-TIME BEHAVIOR OF THE OBSERVABLES IN IRREVERSIBLE REACTIONS IN LIQUID SOLUTIONS, Chemical physics letters, 246(4-5), 1995, pp. 359-363
General kinetic laws of the attainment of steady state values by the o
bservables in irreversible reactions in liquid solutions have been est
ablished, assuming mixing by free motion in the configuration space (i
ncluding random walks by stochastic jumps of arbitrary length in three
-dimensional infinite space, and arbitrary Markovian stochastic motion
over internal degrees of freedom). Apart from the fact that the above
mentioned attainments of steady state values proceed by the universal
kinetic laws, it is to be noted that they are determined solely by th
e values of macroscopic quasi-equilibrium observables.