LONG-TIME BEHAVIOR OF THE OBSERVABLES IN IRREVERSIBLE REACTIONS IN LIQUID SOLUTIONS

Citation
Aa. Kipriyanov et Ab. Doktorov, LONG-TIME BEHAVIOR OF THE OBSERVABLES IN IRREVERSIBLE REACTIONS IN LIQUID SOLUTIONS, Chemical physics letters, 246(4-5), 1995, pp. 359-363
Citations number
23
Categorie Soggetti
Physics, Atomic, Molecular & Chemical
Journal title
ISSN journal
00092614
Volume
246
Issue
4-5
Year of publication
1995
Pages
359 - 363
Database
ISI
SICI code
0009-2614(1995)246:4-5<359:LBOTOI>2.0.ZU;2-I
Abstract
General kinetic laws of the attainment of steady state values by the o bservables in irreversible reactions in liquid solutions have been est ablished, assuming mixing by free motion in the configuration space (i ncluding random walks by stochastic jumps of arbitrary length in three -dimensional infinite space, and arbitrary Markovian stochastic motion over internal degrees of freedom). Apart from the fact that the above mentioned attainments of steady state values proceed by the universal kinetic laws, it is to be noted that they are determined solely by th e values of macroscopic quasi-equilibrium observables.