MULTIPLE STEADY-STATES AND INSTABILITY IN DISTILLATION - IMPLICATIONSFOR OPERATION AND CONTROL

The fact that distillation columns, even in the ideal binary case, may display multiple steady states and unstable operating points has only recently been recognized. This article addresses some implications of these phenomena for the operation and control of distillation columns . Under manual operation, the multiplicity and instability will result in inability to reach separations corresponding to unstable operating points and may furthermore cause abrupt changes and hysteresis in ope rating conditions. It is shown that an unstable operating point may be stabilized by feedback control of a single product composition or tra y temperature (one-point control). The steady-state multiplicity does, in this case, not represent any severe limitation in operation, but i f the control is not sufficiently tight, the column may settle in sust ained oscillations (stable limit cycle). Finally, the impact of open-l oop instability on the achievable closed-loop performance with both pr oduct compositions under feedback control is discussed.