STUDIES ON SULFINATODEHALOGENATION .27. MECHANISM STUDIES USING SPIN-TRAPPING TECHNIQUES

Authors
HUANG BN WU FH ZHOU CM
Citation
Bn. Huang et al., STUDIES ON SULFINATODEHALOGENATION .27. MECHANISM STUDIES USING SPIN-TRAPPING TECHNIQUES, Journal of fluorine chemistry, 75(1), 1995, pp. 1-5
Citations number
16
Categorie Soggetti
Chemistry Inorganic & Nuclear","Chemistry Inorganic & Nuclear
Journal title
Journal of fluorine chemistry → ACNP
ISSN journal
00221139
Volume
75
Issue
1
Year of publication
1995
Pages
1 - 5
Database
ISI
SICI code
0022-1139(1995)75:1<1:SOS.MS>2.0.ZU;2-K
Abstract
Some polyfluoroalkyl t-butyl nitroxide radicals have been generated by using 2-methyl-2-nitrosopropane (MNP) to trap polyfluoroalkyl radical s formed in sulfinatodehalogenation reactions. Several oxyanion radica ls of sulfur generated directly from sulfinatodehalogenation reagents are observed for the first time. All these support the SET mechanism f or the sulfinatodehalogenation reaction proposed to account for the ex perimental results.