The transmittance of a free-standing Saran film, 4260 Angstrom thick,
has been measured by means of synchrotron radiation in the 45-584-Angs
trom wavelength region. The transmittance was calculated by means of t
he elemental composition of the film material as determined by x-ray p
hotoelectron spectroscopy and the optical constants as derived from at
omic-scattering factors. The calculated transmittance agreed with the
measured transmittance in the 45-150-Angstrom wavelength region. The c
alculated transmittance was significantly lower than that measured for
the wavelength range 150-340 Angstrom. This difference implies that m
olecular effects that are not accounted for by atomic-scattering facto
rs become increasingly important at the longer wavelengths. (C) 1995 O
ptical Society of America