BIOMIMETIC HYDROXYLATION OF METHYL 4-HYDROXYBENZOATE WITH MOLECULAR-OXYGEN IN PRESENCE OF SODIUM DITHIONITE AND FLAVIN MONONUCLEOTIDE IN AOT REVERSE MICELLES

Citation
Sms. Chauhan et A. Awasthi, BIOMIMETIC HYDROXYLATION OF METHYL 4-HYDROXYBENZOATE WITH MOLECULAR-OXYGEN IN PRESENCE OF SODIUM DITHIONITE AND FLAVIN MONONUCLEOTIDE IN AOT REVERSE MICELLES, Indian journal of chemistry. Sect. B: organic chemistry, including medical chemistry, 34(10), 1995, pp. 872-875
Citations number
32
Categorie Soggetti
Chemistry Inorganic & Nuclear
ISSN journal
03764699
Volume
34
Issue
10
Year of publication
1995
Pages
872 - 875
Database
ISI
SICI code
0376-4699(1995)34:10<872:BHOM4W>2.0.ZU;2-2
Abstract
The biomimetic hydroxylation of methyl 4-hydroxybenzoate with molecula r oxygen has been observed in the presence of sodium dithionite and fl avin mononucleotide in AOT reverse micelles in different reaction cond itions. Formation of methyl 3,4-dihydroxybenzoate in AOT reverse micel les is more than in biphasic conditions and is governed by water to su rfactant ratio (W-O) and pH of the reaction media.