SYNTHETIC EXPERIMENTS IN LIGNANS .15. REDUCTIVE REARRANGEMENTS OF 2,6-DIARYL-3,7-DIOXABICYCLO[3,3.0]OCTANE LIGNANS WITH ALCL3 AND (C2H5)(3)SIH

Authors
ANJANEYULU A KUMAR DS VENKATESWARLU R KAMAKSHI C
Citation
A. Anjaneyulu et al., SYNTHETIC EXPERIMENTS IN LIGNANS .15. REDUCTIVE REARRANGEMENTS OF 2,6-DIARYL-3,7-DIOXABICYCLO[3,3.0]OCTANE LIGNANS WITH ALCL3 AND (C2H5)(3)SIH, Indian journal of chemistry. Sect. B: organic chemistry, including medical chemistry, 34(10), 1995, pp. 897-899
Citations number
8
Categorie Soggetti
Chemistry Inorganic & Nuclear
Journal title
Indian journal of chemistry. Sect. B: organic chemistry, including medical chemistry → ACNP
ISSN journal
03764699
Volume
34
Issue
10
Year of publication
1995
Pages
897 - 899
Database
ISI
SICI code
0376-4699(1995)34:10<897:SEIL.R>2.0.ZU;2-C
Abstract
The mixture of AlCl3 and (C2H5)(3)SiH has been found to cleave the ben zyl ethers of the lignans, gmelinol, paulownin, wodeshiol and eudesmin leading to a tetrahydrofuran, a tetrahydropyran or an aryltetralin de rivative by reductive rearrangement.