The addition of various extreme pressure (EP) and anti-wear (AW) addit
ives in lubricating oil is an important and effective way to reduce fr
iction and wear. The application of chemico-thermal treatments on the
surface of materials is another effective way for improving the tribol
ogical behaviour of rubbing pairs. In this paper the synergistic effec
ts of two EP/AW additives, sulphurized olefin and tricresyl phosphate,
with an oxynitrided surface of 1045 steel on the tribological behavio
ur were studied systematically on a 'ball-on-disk' testing machine. An
excellent result of increasing load-carrying capacity and reducing fr
iction and wear was obtained. The mechanism of this synergistic effect
was discussed based on the microanalysis of surface film by AES and X
PS.