M. Gothelid et al., METAL-SEMICONDUCTOR FLUCTUATION IN THE SN ADATOMS IN THE SI(111)-SN AND GE(111)-SN (ROOT-3X-ROOT-3)R30-DEGREES RECONSTRUCTIONS, Physical review. B, Condensed matter, 52(20), 1995, pp. 14352-14355
The two components of the Sn 4d core level in the Si(111)-Sn and Ge(11
1)-Sn. (root 3 X root 3)R30 degrees structures are proposed to arise f
rom semiconductor-metal fluctuations in the Sn adatom layer. Adsorptio
n of potassium on the Si(111)-Sn (root 3 X root 3)R30 degrees surface
suppresses the metallic component and shifts the tin into a purely sem
iconducting phase with a filled dangling bond state.