Dpf. Desouza et al., IMPURE ZIRCONIA ELECTRICAL-CONDUCTIVITY ENHANCEMENT BY RARE-EARTH MINORITY IONS IN THE Y2O3 RE(2)O(3) ZRO2 SYSTEM, Journal of Materials Science, 30(17), 1995, pp. 4355-4362
Impure zirconia stabilized by 12 wt% yttria concentrate (85 wt% Y2O3+1
5 wt% rare-earth (RE)) was found to have high grain and grain-boundary
electrical conductivities. The influence of the RE on the segregation
of impurities was studied for four different compositions. Microstruc
ture features are evidence for the enhanced segregation of impurities
due to RE ions. The increased grain and grain-boundary conductivities
are a consequence of the segregation of impurities.