K. Zdunek et H. Grigoriew, NANOPOROSITY OF AL2O3 COATINGS OBTAINED BY IMPULSE PLASMA DEPOSITION, Journal of Materials Science, 30(17), 1995, pp. 4479-4482
Investigations of the size distribution of nanopores were carried out
for alumina coatings deposited by the impulse plasma method. The singl
e-phase (metastable and stable correspondingly) alumina coatings were
deposited under different conditions of impulse plasma processes. The
investigation of nanopore distribution was carried out using small-ang
le X-ray scattering. Despite the different phase composition of the co
atings obtained, the most probable value of nanopores for both alumina
coating materials were practically the same and equal to 5 nm. It app
ears that a coating porosity of the order of nanometres is characteris
tic for all coatings deposited by the impulse plasma method, because p
reviously similar dimensions of nanopores were found for diamond, TiN
and BN. It seems that during the impulse plasma deposition the coating
grows on the substrate surface by condensation of ultra-small particl
es nucleated in the impulse plasma.