F. Ulffmoller et al., MAGMATIC ACTIVITY ON THE IVA PARENT BODY - EVIDENCE FROM SILICATE-BEARING IRON-METEORITES, Geochimica et cosmochimica acta, 59(22), 1995, pp. 4713-4728
Four of the magmatic IVA iron meteorites contain tridymite or clinobro
nzite-orthobronzite-tridymite which are quite unlike silicate assembla
ges in other iron meteorites. The textures, the bulk chemistry, and th
e zoning preserved in the pyroxenes strongly suggest that they are ign
eous cumulates. The pyroxenes have extremely low Fe/Mn-ratios (less th
an 20) and low contents of REEs and other incompatible elements. These
cumulates crystallized from magmas of unusual composition, with some
similarity to terrestrial boninites, at the protobronzite-tridymite co
tectic in the olivine-plagioclase-silica system. A liquidus temperatur
e in the range 1400-1350 degrees C was inferred for the Steinbach mete
orite from the estimated distribution coefficient for Cr in pyroxene (
D-Cr(solid/liquid) similar to 0.66). The low levels of incompatible el
ements show that less than 1% of the residual liquid was trapped in th
e cumulates. During cooling at subsolidus temperatures, most of the pr
otobronzite transformed to orthobronzite and the rest inverted to a fi
ne intergrowth of clino- and orthobronzite. In addition, the igneous z
oning of Ca, Fe, Mg, and Mn was modified by diffusion, whereas Ti, Al,
and Cr were not or only slightly affected. The silica-saturated magma
s could not have evolved in an olivine-rich mantle. We assume that the
magmas became incorporated in the metal core, possibly due to solidif
ication shrinkage of the metal. We propose that the IVA parent magmas
were formed by high degrees of partial melting (>40%) of a chondritic
precursor along the olivine-pyroxene peritectic reaction curve in the
olivine-plagioclase-silica system at low pressures. The precursor may
have been depleted in incompatible elements by a preceding melting epi
sode. The partial melts were then separated from the olivine residue a
nd subsequently reduced to account for the low Fe/Mn-ratios and the un
usually high Si content.