For the analysis of surfaces with poor conductivity the use of the ''d
irect current sputter process'', usual in SNMS, produces unreproducibl
e depth profiles with often widened transition widths. An efficient me
thod for eliminating static charging in the case of non-coducting samp
les is the use of a high-frequency discharge. By comparison of the dir
ect current mode with high frequency mode it is shown, that the use of
SNMS with HF sputtering is the universal analysis method for most mat
rices, technical surfaces as well as oxidic materials. For non-conduct
ing or poorly conducting samples, however, matrix-adjusted factors are
to be used.