Investigations of the electronic and magnetic properties of oxygen ads
orbed on magnetized iron films have been carried out by means of angle
and spin resolving photoelectron spectroscopy. Iron, epitaxially grow
n on W(100) and W(110) crystals, served as the ferromagnetic substrate
. Exchange splittings of the O 2p(x) derived level have been detected,
demonstrating a magnetic coupling between the chemisorbate and the ir
on layer. Variations of the exchange splitting have occurred as a func
tion of the oxygen coverage, photon energy, and emission angle. High o
xygen exposures have lead to a FeO overlayer at the surface.