INTERCALATION OF VOPO4-CENTER-DOT-2H(2)O WITH HYDRONIUM AND POTASSIUM-IONS

Authors
ZIMA V BENES L VOTINSKY J KALOUSOVA J
Citation
V. Zima et al., INTERCALATION OF VOPO4-CENTER-DOT-2H(2)O WITH HYDRONIUM AND POTASSIUM-IONS, Solid state ionics, 82(1-2), 1995, pp. 33-38
Citations number
16
Categorie Soggetti
Physics, Condensed Matter","Chemistry Physical
Journal title
Solid state ionics → ACNP
ISSN journal
01672738
Volume
82
Issue
1-2
Year of publication
1995
Pages
33 - 38
Database
ISI
SICI code
0167-2738(1995)82:1-2<33:IOVWHA>2.0.ZU;2-F
Abstract
Intercalation compounds HxVOPO4 . yH(2)O (x = 0.3-1.0; y = 2.0-3.6) an d KxVOPO4 . yH(2)O (x = 0.2-0.98; y = 1) were prepared by redox interc alation of VOPO4 . 2H(2)O with acetone solutions of hydroquinone and p otassium iodide respectively. Time course of reactions, X-ray diffract ion and ac conductivity of prepared compounds were studied. The decrea se of conductivity with increasing content of guest was observed. The activation energy of conductivity of HxVOPO4 . yH(2)O was calculated f rom the Arrhenius plot. The content of interlayer water increases duri ng intercalation of hydronium ions as it was determined by DTA.