SYNTHESIS AND CRYSTAL-STRUCTURE OF TRILEA D-DIPHOSPHATO-BORATE-PHOSPHATE, A COMPOUND WITH A (1)(INFINITY)[(PO4)(2)BPO4](6-)-ANION

Authors
PARK CH BLUHM K
Citation
Ch. Park et K. Bluhm, SYNTHESIS AND CRYSTAL-STRUCTURE OF TRILEA D-DIPHOSPHATO-BORATE-PHOSPHATE, A COMPOUND WITH A (1)(INFINITY)[(PO4)(2)BPO4](6-)-ANION, Zeitschrift fur Naturforschung. B, A journal of chemical sciences, 50(11), 1995, pp. 1617-1622
Citations number
22
Categorie Soggetti
Chemistry Inorganic & Nuclear","Chemistry Inorganic & Nuclear
Journal title
Zeitschrift fur Naturforschung. B, A journal of chemical sciences → ACNP
ISSN journal
09320776
Volume
50
Issue
11
Year of publication
1995
Pages
1617 - 1622
Database
ISI
SICI code
0932-0776(1995)50:11<1617:SACOTD>2.0.ZU;2-Q
Abstract
Single crystals of Pb-3[(PO4)(2)BPO4] were obtained by melting B2O3, P 2O5 and PbO at 960 degrees C. The structure is related to the Ba-3[(PO 4)(2)BPO4] type X-ray investigations on single crystals led to the spa ce group Pbca-D-2h(15) (Nr. 61) with a = 694.6(1), b = 1419.9(3), c = 2111.6(2) pm, Z = 8. Boron and phosphorus are tetrahedrally coordinate d by oxygen. The polyhedra form one-dimensional infinite helices that contain two additional PQ(4) groups connected to the BO4-unit. Lead is eightfold coordinated by oxygen. The relation to the crystal structur e of Ba-3[(PO4)(2)BPO4] is discussed.