The properties of an oxyfluoride glass ceramic that possesses high tra
nsparency after ceramming are described. Approximately 25 vol % of thi
s material is comprised of cubic, fluoride nanocrystals and the remain
der is a predominantly oxide glass. When doped with Pr+3, the fluoresc
ence lifetime at 1300 nm is longer than in a fluorozirconate glass, su
ggesting that a significant fraction of the rare-earth dopant is prefe
rentially partitioned into the fluoride crystal phase. This material h
as the added advantage of being compatible with ambient air processing
. (C) 1995 American Institute of Physics.