SYNTHESIS, CHARACTERIZATION AND CATALYTIC PROPERTIES OF 2 NOVEL VANADO-ALUMINOSILICATES WITH EU-1 AND ZSM-22 STRUCTURES

Authors
CHATTERJEE M BHATTACHARYA D VENKATATHRI N SIVASANKER S
Citation
M. Chatterjee et al., SYNTHESIS, CHARACTERIZATION AND CATALYTIC PROPERTIES OF 2 NOVEL VANADO-ALUMINOSILICATES WITH EU-1 AND ZSM-22 STRUCTURES, Catalysis letters, 35(3-4), 1995, pp. 313-326
Citations number
26
Categorie Soggetti
Chemistry Physical
Journal title
Catalysis letters → ACNP
ISSN journal
1011372X
Volume
35
Issue
3-4
Year of publication
1995
Pages
313 - 326
Database
ISI
SICI code
1011-372X(1995)35:3-4<313:SCACPO>2.0.ZU;2-F
Abstract
The synthesis in the presence of alkali ions of two novel vanadium con taining zeolites V-Al-EU-1 and V-Al-ZSM-22 is reported. Both V4+- and V5+-ions are present in as-synthesized samples. Cyclic voltammograms o f the samples reveal the presence of two types of V5+ in the calcined samples. A weak shoulder at similar to 980 cm(-1) is observed in the I R spectra of the calcined samples. On extraction with acid a sharp ban d appears at similar to 960 cm(-1). The acid washed samples are more a ctive in the hydroxylation of phenol and the oxidation of toluene (wit h H2O2) than the calcined samples.