THE POLARIZABILITY OF SOME DEUTERATED HYDROCARBONS

Citation
Dg. Legrand et Gl. Gaines, THE POLARIZABILITY OF SOME DEUTERATED HYDROCARBONS, Journal of physical chemistry, 98(18), 1994, pp. 4842-4844
Citations number
15
Categorie Soggetti
Chemistry Physical
ISSN journal
00223654
Volume
98
Issue
18
Year of publication
1994
Pages
4842 - 4844
Database
ISI
SICI code
0022-3654(1994)98:18<4842:TPOSDH>2.0.ZU;2-9
Abstract
The refractive indices of perdeuterated hydrocarbons n-hexane-d(14), h eptane-d(16), and octane-d(18), benzene-d(6), toluene-d(8), and ethylb enzene-d(10) have been measured at room temperature at five different wavelengths. The polarizabilities of these compounds have been compute d as a function of wavelength using the Lorentz-Lorenz equation and at infinite wavelength using the Cauchy equation. In all cases, the pola rizabilities of the deuterated compounds are less than the correspondi ng nondeuterated compounds.