G. Rychlicki et Ap. Terzyk, INDISPENSABILITY OF THE USE OF CALORIMETRIC MEASUREMENTS FOR THE DESCRIPTION OF ADSORPTION PROCESSES IN MICROPOROUS SYSTEMS, Journal of thermal analysis, 45(5), 1995, pp. 961-965
The role of calorimetry in adsorption is shortly reviewed. The differe
nces between calorimetric adsorption heats and those calculated from C
lausius-Clapeyron equation for the systems ethanol-activated carbons a
re presented. Obtained results, together with the results presented pr
eviously for other adsorbates, confirm that calorimetry is indispensab
le for a real thermodynamical description of the adsorption process in
this type of system.