We have deposited iron/alumina multilayers on saphhire wafers using RF
magnetron sputtering. In the aim to study their thermal behaviour, mu
ltilayers have been annealed in a tubular furnace under a controlled a
tmosphere and characterized by x-ray diffraction, room-temperature bul
k magnetization and Fe-57 Mossbauer spectroscopy. Without treatment, F
e/Al2O3 multilayers consist of alternating amorphous alumina and polyc
rystalline iron. For thermal treatments above 773 K, we observe the co
existence of Fe2+, and metallic BCC and FCC Fe. The presence of these
phases is related to the respective thicknesses of the Fe and Al2O3 la
yers for three different samples. Competition between the interfacial
and shape magnetic anisotropy is found to be strongly dependent on the
presence of FCC iron.