LOCAL-STRUCTURE OF GLASSES IN THE AS2S3-SB2S3 SYSTEM

Authors
RAGHNI MAE LIPPENS PE OLIVIERFOURCADE J JUMAS JC
Citation
Mae. Raghni et al., LOCAL-STRUCTURE OF GLASSES IN THE AS2S3-SB2S3 SYSTEM, Journal of non-crystalline solids, 193, 1995, pp. 191-194
Citations number
12
Categorie Soggetti
Material Science, Ceramics
Journal title
Journal of non-crystalline solids → ACNP
ISSN journal
00223093
Volume
193
Year of publication
1995
Pages
191 - 194
Database
ISI
SICI code
0022-3093(1995)193:<191:LOGITA>2.0.ZU;2-P
Abstract
The local structure of glasses of composition As-2(1-x)Sb2xS3 with x = 0-0.8 is studied by different techniques: Sb-121 Mossbauer spectrosco py, infrared and optical absorption experiments. The results are consi stent with a model of the glasses formed by a random distribution of A sS3 and SbS3 trigonal pyramidal units connected by sulphur atoms. The variations in the experimental data with Sb2S3 concentration can be co rrelated with the substitution of Sb atoms for As atoms.