Xw. Luo et al., STUDY ON THE SORPTION OF WATER INTO EPOXY-RESINS BY MEANS OF ELECTROCHEMICAL IMPEDANCE SPECTROSCOPY, Macromolecular rapid communications, 16(12), 1995, pp. 941-946
In this work the relationship between structure and water sorption for
epoxy films was studied using electrochemical impedance spectroscopy.
It is shown that the electrochemical impedance spectroscopy can be ap
plied to obtain information about the amount of water absorbed by the
epoxy film and the water permeation through the film, while only the a
mount of water absorbed is obtained from the ''sorption method''. The
free volume is the decisive factor for both the amount of water in the
cured epoxy film and water permeation through the film.