-TETRAAZACYCLOPENT[CD]AZULENE-1(2H),4(3H)-DITHIONE

Citation
Dg. Billing et al., -TETRAAZACYCLOPENT[CD]AZULENE-1(2H),4(3H)-DITHIONE, Acta crystallographica. Section C, Crystal structure communications, 51, 1995, pp. 2354-2356
Citations number
6
Categorie Soggetti
Crystallography
ISSN journal
01082701
Volume
51
Year of publication
1995
Part
11
Pages
2354 - 2356
Database
ISI
SICI code
0108-2701(1995)51:<2354:->2.0.ZU;2-P
Abstract
The title compound, C11H18N4S3, contains elongated N-S bonds [1.877(1) and 1.903(1) Angstrom] which are greater by 7.9 and 9.4%, respectivel y, than the two-centre two-electron N-S bond [1.74 Angstrom; Alien, Ke nnard, Watson, Brammer, Orpen & Taylor (1987). J. Chem. Soc. Perkin Tr ans. 2, pp. S1-S19]. The lengths of corresponding bonds and the size o f the corresponding bond angles in the two halves of the triheterapent alene framework are very similar, differing from one another at most b y 0.027 Angstrom and 0.83 degrees, respectively.