4,6-DIMETHOXY-3-METHYL-1,3,5-TRIAZIN-2(3H)-ONE AND THOXY-3,5-DIMETHYL-1,3,5-TRIAZINE-2,4(3H,5H)-DIONE

Authors
HANDELSMANBENORY E BOTOSHANSKY M KAFTORY M
Citation
E. Handelsmanbenory et al., 4,6-DIMETHOXY-3-METHYL-1,3,5-TRIAZIN-2(3H)-ONE AND THOXY-3,5-DIMETHYL-1,3,5-TRIAZINE-2,4(3H,5H)-DIONE, Acta crystallographica. Section C, Crystal structure communications, 51, 1995, pp. 2421-2424
Citations number
11
Categorie Soggetti
Crystallography
Journal title
Acta crystallographica. Section C, Crystal structure communications → ACNP
ISSN journal
01082701
Volume
51
Year of publication
1995
Part
11
Pages
2421 - 2424
Database
ISI
SICI code
0108-2701(1995)51:<2421:4AT>2.0.ZU;2-X
Abstract
2,4,6-Trimethoxy-1,3,5-triazine, (I), undergoes methyl transfer in a f ew stages to 1,3,5-trimethyl-2,4,6-trioxohexahydro-s-triazine, (IV). T he crystal structures of the two intermediates, 4,6-dimethoxy-3-methyl -1,3,5-triazin-2(3H)-one, (II) (C6H9N3O3), and hoxy-3,5-dimethyl-1,3,5 -triazine-2,4(3H,5H)-dione, (III) (C6H9N3O3), are described. Molecules of (II) form a layer structure made up of infinite ribbons. Molecules of (III) related by an inversion centre are arranged in pairs.