A STUDY OF THE EFFECT OF CATALYST ON STEREOCHEMISTRY IN THE HYDROGENATION OF NYL)-N-METHYL-2-(N-PYRROLIDINYL)-1-CYCLOHEXENAMINE

Authors
MATECKA D DECOSTA BR
Citation
D. Matecka et Br. Decosta, A STUDY OF THE EFFECT OF CATALYST ON STEREOCHEMISTRY IN THE HYDROGENATION OF NYL)-N-METHYL-2-(N-PYRROLIDINYL)-1-CYCLOHEXENAMINE, Synthetic communications, 24(11), 1994, pp. 1531-1540
Citations number
9
Categorie Soggetti
Chemistry Inorganic & Nuclear
Journal title
Synthetic communications → ACNP
ISSN journal
00397911
Volume
24
Issue
11
Year of publication
1994
Pages
1531 - 1540
Database
ISI
SICI code
0039-7911(1994)24:11<1531:ASOTEO>2.0.ZU;2-Y
Abstract
Catalytic hydrogenation of nyl)-N-methyl-2-(1-pyrrolidinyl)-1-cyclohex enamine (3) gave mainly 1R,2S-cis-N-(menthyloxycarbonyl)- and bonyl)-N -methyl-2-(1-pyrrolidinyl)cyclohexylamines 7 and 8 with diasterostereo selectivity favoring the 1S,2R-isomer 8.