In the Nd-Ba-Cu-O system, a directional structure produced by a perite
ctic reaction has been observed. On heating, the sintered Nd1Ba2CU3O6delta (Nd123) precursor formed a rod-like directional structure of Nd4
Ba2-Cu2O10 (Nd422) phase. These Nd422 rods became thicker from the mel
ting interface to the solidified interface. The [100] direction of Nd4
22 crystal is parallel to the axis of Nd422 rod and the sample pulling
direction. Moreover, Nd422 rod spacing was observed as a function of
growth rate and decreased with an increase of growth rate. In addition
, with an increase of growth rate, Nd123 solidified interface morpholo
gies changed from planar, cellular to equiaxed.