Nj. Wu et al., THIN-FILM DEPOSITION AND INTERFACE CHARACTERIZATION OF YBCO ON LINBO3SUBSTRATES, Journal of materials research, 10(12), 1995, pp. 3009-3015
High transition temperature superconducting YBa2CU3O7-x (YBCO) thin fi
lms have been epitaxially grown on YZ-cut LiNbO3 (LNO) substrates by t
he pulsed laser deposition technique. The interface between YBCO and L
NO has been systematically investigated by scanning electron microscop
y, atomic force microscopy, Auger electron spectroscopy, and x-ray pho
toelectron spectroscopy. Off-stoichiometry LiNbOx phases are found to
segregate on the substrate surface because of lithium and oxygen vacan
cies formed during the high temperature YBCO growth. These submicromet
er particles are observed along the Z-axis on the X-Z plane of LNO wit
h height of similar to 30 nm above the LNO surface. This rough growth
surface results in YBa2Cu3O7-x thin films grown on the LNO surface tha
t have reduced J(c) and T-c, possibly limiting the use of YBCO/LNO het
erostructures for surface acoustic wave (SAW) devices.