The simultaneous determination of light element contamination levels a
nd accurate nitrogen-to-metal ratios in nitride thin films deposited o
n silicon substrates is demonstrated by using alpha-particle beam ener
gies in the range 3-4 MeV. In this energy range, significant light ele
ment sensitivity enhancements are observed, while the heavy elements s
how classical Rutherford behavior. The use of resonance scattering at
different resonance energies is shown to be the method of choice for a
nalyzing BN films on silicon. Also, a technique is suggested for analy
zing very thin films in which an aluminum foil substrate and buffer la
yer are used to enhance sensitivities.