KINETICS OF TECHNETIUM REACTIONS .13. REDUCTION OF TC(VII) WITH HYDROXYETHYLHYDRAZINE

Authors
GOMONOVA TV KOLTUNOV VS
Citation
Tv. Gomonova et Vs. Koltunov, KINETICS OF TECHNETIUM REACTIONS .13. REDUCTION OF TC(VII) WITH HYDROXYETHYLHYDRAZINE, Radiochemistry, 37(5), 1995, pp. 381-383
Citations number
7
Categorie Soggetti
Chemistry Analytical","Chemistry Inorganic & Nuclear
Journal title
Radiochemistry → ACNP
ISSN journal
10663622
Volume
37
Issue
5
Year of publication
1995
Pages
381 - 383
Database
ISI
SICI code
1066-3622(1995)37:5<381:KOTR.R>2.0.ZU;2-4
Abstract
2-Hydroxyethylhydrazine reduces Tc(VII) to Tc(IV) with formation of Te Cl5- ions. The rate of this reaction in HCl solution obeys the equatio n -d[Tc(VII)]/dt = k[Tc(VII)][HOC2H4N2H4+](0.9)[H+](1.4), where k = (8 .75+/-0.46) x 10(-3) 1(2.3) mol(-2.3) min(-1) at 25 degrees C and mu = 3.1. The reaction mechanism is similar to that of the reaction of Tc( VII) with unsubstituted hydrazine.