Molecular self-assembly of supported monolayers can produce a variety
of structures with different types of surface functional groups and wi
th varied topography. Such structural flexibility promises many applic
ations. In addition, strategies for precision chemical patterning have
evolved which expand the possibilities. Real applications of these mo
nolayers will require precise control of structural features which in
turn depends critically upon improved understanding of such factors as
formation mechanisms and mixed composition phase stability. Recent ad
vances show that such an understanding should evolve in the future.