ASYMMETRIC CATALYSIS OF CARBONYL-ENE AND ALDOL REACTIONS WITH FLUORALBY CHIRAL BINAPHTHOL-DERIVED TITANIUM COMPLEX

Authors
MIKAMI K YAJIMA T TAKASAKI T MATSUKAWA S TERADA M UCHIMARU T MARUTA M
Citation
K. Mikami et al., ASYMMETRIC CATALYSIS OF CARBONYL-ENE AND ALDOL REACTIONS WITH FLUORALBY CHIRAL BINAPHTHOL-DERIVED TITANIUM COMPLEX, Tetrahedron, 52(1), 1996, pp. 85-98
Citations number
54
Categorie Soggetti
Chemistry Inorganic & Nuclear
Journal title
Tetrahedron → ACNP
ISSN journal
00404020
Volume
52
Issue
1
Year of publication
1996
Pages
85 - 98
Database
ISI
SICI code
0040-4020(1996)52:1<85:ACOCAA>2.0.ZU;2-X
Abstract
The chiral titanium complex-catalyzed ene-type reaction and the Mukaiy ama aldol reaction with fluoral are shown to serve as an efficient rou te to the enantioselective and diastereoselective synthesis of CF3-sub stituted components of biological and synthetic importance.