INTERACTIONS IN SOLUTIONS - THE INTERPLAY BETWEEN SOLUTE SOLVATION AND SOLUTE SOLUTE INTERACTIONS

Authors
LILLEY TH
Citation
Th. Lilley, INTERACTIONS IN SOLUTIONS - THE INTERPLAY BETWEEN SOLUTE SOLVATION AND SOLUTE SOLUTE INTERACTIONS, Pure and applied chemistry, 66(3), 1994, pp. 429-434
Citations number
12
Categorie Soggetti
Chemistry
Journal title
Pure and applied chemistry → ACNP
ISSN journal
00334545
Volume
66
Issue
3
Year of publication
1994
Pages
429 - 434
Database
ISI
SICI code
0033-4545(1994)66:3<429:IIS-TI>2.0.ZU;2-3
Abstract
Some results are presented for the partial molar heat capacities and t he enthalpies of hydration of amides in water; both can be represented using a group additivity approach. Results are also given for various enthalpic interaction coefficients of some amides in water. From the information given a general chemical principal is postulated namely th at the more strongly solutes are solvated the less will be their prope nsity to interact with other solutes.