AUTORECYCLING SYSTEM FOR THE SPECIFIC 1,4-REDUCTION OF ALPHA,BETA-UNSATURATED CARBONYL-COMPOUNDS CATALYZED BY 1,5-DIHYDRO-5-DEAZAFLAVIN

Authors
NAGAMATSU T KURODA K MIMURA N YANADA R YONEDA F
Citation
T. Nagamatsu et al., AUTORECYCLING SYSTEM FOR THE SPECIFIC 1,4-REDUCTION OF ALPHA,BETA-UNSATURATED CARBONYL-COMPOUNDS CATALYZED BY 1,5-DIHYDRO-5-DEAZAFLAVIN, Journal of the Chemical Society. Perkin transactions. I, (9), 1994, pp. 1125-1128
Citations number
13
Categorie Soggetti
Chemistry Inorganic & Nuclear
Journal title
Journal of the Chemical Society. Perkin transactions. I → ACNP
ISSN journal
0300922X
Issue
9
Year of publication
1994
Pages
1125 - 1128
Database
ISI
SICI code
0300-922X(1994):9<1125:ASFTS1>2.0.ZU;2-2
Abstract
A useful autorecycling system for the specific 1,4-reduction of alpha, beta-unsaturated carbonyl compounds to the corresponding saturated car bonyl compounds catalysed by a 10-aryl-5-deazaflavin in formic acid is reported. The specific reduction behaviour toward alpha,beta-unsatura ted carbonyl compounds is interpreted in terms of frontier molecular o rbital theory (PM3 method).