HORSE RADISH PEROXIDASE-CATALYZED OXIDATIVE COUPLING OF METHYL SINAPATE TO GIVE DIASTEREOISOMERIC SPIRO DIMERS

Authors
SETALA H PAJUNEN A KILPELAINEN I BRUNOW G
Citation
H. Setala et al., HORSE RADISH PEROXIDASE-CATALYZED OXIDATIVE COUPLING OF METHYL SINAPATE TO GIVE DIASTEREOISOMERIC SPIRO DIMERS, Journal of the Chemical Society. Perkin transactions. I, (9), 1994, pp. 1163-1165
Citations number
11
Categorie Soggetti
Chemistry Inorganic & Nuclear
Journal title
Journal of the Chemical Society. Perkin transactions. I → ACNP
ISSN journal
0300922X
Issue
9
Year of publication
1994
Pages
1163 - 1165
Database
ISI
SICI code
0300-922X(1994):9<1163:HRPOCO>2.0.ZU;2-E
Abstract
The oxidative coupling of methyl sinapate with H2O2/horse radish perox idase at pH 4 in the presence of methanol gives dimeric spiro structur es of a novel type. The crystal structures of two diastereoisomers hav e been determined. The coupling reaction shows some three selectivity.