Dl. Ivanov et Bs. Yakovlev, DETERMINATION OF INITIAL DISTRIBUTION OF THERMALIZED ION-PAIRS IN HYDROCARBON GLASS, High energy chemistry, 29(6), 1995, pp. 378-384
A new method for the determination of an initial spatial distribution
function f(0)(r) for thermalized geminate electron-ion pairs is sugges
ted. Various experimental values (yield of free charges, quantum yield
of photostimulated recombination, etc.) were expressed through f(0)(r
) in terms of the diffusion model of electron motion. The real functio
n was substituted for a linear combination of functions of a known typ
e with initially indefinite weighting factors. This combination was us
ed to describe experimental data. By solving the obtained set of equat
ions, it was possible to reconstruct the function f(0)(r). Based on th
e results of the calculations, conclusions are drawn concerning the be
havior of f(0)(r) in various regions of r value.