ROLE OF SPATIAL ARRANGEMENT OF REACTANTS IN SOLID-PHASE CHEMICAL CHAIN-REACTIONS AT ULTRALOW TEMPERATURES

Authors
MISOCHKO EY
Citation
Ey. Misochko, ROLE OF SPATIAL ARRANGEMENT OF REACTANTS IN SOLID-PHASE CHEMICAL CHAIN-REACTIONS AT ULTRALOW TEMPERATURES, High energy chemistry, 29(6), 1995, pp. 397-400
Citations number
17
Categorie Soggetti
Chemistry Physical
Journal title
High energy chemistry → ACNP
ISSN journal
00181439
Volume
29
Issue
6
Year of publication
1995
Pages
397 - 400
Database
ISI
SICI code
0018-1439(1995)29:6<397:ROSAOR>2.0.ZU;2-D
Abstract
The conditions for chain propagation are discussed for low-temperature solid-phase reactions occurring in the absence of translational diffu sion of the reactants. It was shown that the chain length and the geom etry of its propagation related to distribution of the reactants over the lattice points and hot atoms formed in exothermic processes are in volved in chain propagation.