SYNTHESIS OF [1,2,5]OXADIAZOLO[3,4-E][1,2,3,4]TETRAZINE 4,6-DI-N-OXIDE

Authors
CHURAKOV AM IOFFE SL TARTAKOVSKY VA
Citation
Am. Churakov et al., SYNTHESIS OF [1,2,5]OXADIAZOLO[3,4-E][1,2,3,4]TETRAZINE 4,6-DI-N-OXIDE, Mendeleev communications, (6), 1995, pp. 227-228
Citations number
5
Categorie Soggetti
Chemistry
Journal title
Mendeleev communications → ACNP
ISSN journal
09599436
Issue
6
Year of publication
1995
Pages
227 - 228
Database
ISI
SICI code
0959-9436(1995):6<227:SO[4>2.0.ZU;2-Y
Abstract
Treatment of 3-amino-4-(tert-butyl)azoxyfurazan with NO2BF4 in MeCN gi ves [1,2,5]oxadiazolo[3,4-e][1,2,3,4]tetrazine 4,6-di-N-oxide 2; N-15 labelling experiments allowed the spectra of 2 to be fully assigned an d provided support for the proposed structure. Diazonium oxide cation is proposed as the intermediate in ring closure.