LOW-TEMPERATURE FREE-RADICAL ADDITION-REACTIONS IN SOLID ARGON - F+C2H4, AN EPR STUDY

Authors
BENDERSKII VA GOLDSCHLEGER AU AKIMOV AV MISOCHKO EY WIGHT CA
Citation
Va. Benderskii et al., LOW-TEMPERATURE FREE-RADICAL ADDITION-REACTIONS IN SOLID ARGON - F+C2H4, AN EPR STUDY, Mendeleev communications, (6), 1995, pp. 245-247
Citations number
9
Categorie Soggetti
Chemistry
Journal title
Mendeleev communications → ACNP
ISSN journal
09599436
Issue
6
Year of publication
1995
Pages
245 - 247
Database
ISI
SICI code
0959-9436(1995):6<245:LFAISA>2.0.ZU;2-S
Abstract
Ultraviolet laser photolysis of dilute mixtures of F-2 and C2H4 in sol id argon form a 2-fluoroethyl radical by addition of translationally ' hot' as well as thermal F atoms to ethene; at T>20 K the major channel is the thermal reaction, which converts up to 25% of ethene to 2-fluo roethyl radical.