Ql. Xie et al., SECULAR TRENDS IN THE MELTING DEPTHS OF MANTLE PLUMES - EVIDENCE FROMHFSE REE SYSTEMATICS OF ARCHEAN HIGH-MG LAVAS AND MODERN OCEANIC BASALTS/, Chemical geology, 126(1), 1995, pp. 29-42
Al-depleted komatiites and associated Fe-tholeiites from Boston Townsh
ip, Abitibi belt (similar to 2.7 Ga), Canada, are characterized by the
conjunction of low Al2O3/TiO2 (4-5) ratios, low Sc and Y contents, an
d HREE depletion [(Gd/Yb)(n) = 1.7-2.3], with negative P, Zr and Hf an
omalies relative to MREE on primitive-mantle-normalized diagrams (P/Nd
= 23-36; Zr/Sm = 13-18; Hf/Sm = 0.3-0.5). Enriched high-Mg tholeiites
(EHMT) from the Norseman area (similar to 2.7 Ga), Westem Australia,
are characterized by low Al2O3/TiO2 (4.0-4.7), fractionated HREE [(Gd/
Yb)(n) = 2.3-2.5], and negative P anomalies (P/Nd = 21-26), but near-c
hondritic Zr/Sm (23-27 vs. 25) and Hf/Sm (0.6-0.8 vs. 0.7) ratios. In
both areas there are tholeiites with flat REE patterns derived from a
distinct mantle source than the komatiites and EHMT. Different HFSE an
d REE systematics between the two late Archean high-Mg lavas are inter
preted as partial melting of mantle plumes with different residual min
erals at different depths; Boston Township Al-depleted komatiites may
have been derived from partial melting of a plume with majorite garnet
in the residue at pressures between 14 and 24 GPa, whereas Norseman E
HMT may have been generated either by low-degree partial melting with
a olivine + orthopyroxene + clinopyroxene + garnet residue at pressure
s <6 GPa, or more advanced melting with pyrope garnet in the residue a
t pressures between 6 and 14 GPa. Comparison of HFSE/REE systematics b
etween Archean high-Mg lavas and modem OIB indicates that most modem O
IB are featured by low Al2O3/TiO2 (4-7), P/Nd (50-60) and fractionated
HREE [(Gd/Yb)(n) = 2-3], but near-chondritic Zr/Sm (24-25) and Hf/Sm
(0.6-0.7) ratios, similar to Norseman EHMT, consistent with low-degree
partial melting with garnet in the residue at low pressures. Partial
melting of Archean plumes which generated Al-depleted komatiites may h
ave occurred at greater depths than that of modem plumes. HFSE/REE sys
tematics of plume-derived volcanic rocks records decreasing melting de
pths of mantle plume over time, consistent with the secular cooling of
the Earth.