SYNTHESES AND REDOX PROPERTIES OF DIAMINES, TRIAMINES, TETRAAMINES, AND PENTAAMINES

Authors
SASAKI S IYODA M
Citation
S. Sasaki et M. Iyoda, SYNTHESES AND REDOX PROPERTIES OF DIAMINES, TRIAMINES, TETRAAMINES, AND PENTAAMINES, Chemistry Letters, (11), 1995, pp. 1011-1012
Citations number
13
Categorie Soggetti
Chemistry
Journal title
Chemistry Letters → ACNP
ISSN journal
03667022
Issue
11
Year of publication
1995
Pages
1011 - 1012
Database
ISI
SICI code
0366-7022(1995):11<1011:SARPOD>2.0.ZU;2-B
Abstract
A series of di-, tri-, tetra-, and pentaamines were synthesized as pre cursors for corresponding di-, tri-, tetra-, and penta(aminium radical -cations) by the aryl-N bond formation reaction between aryl iodides a nd in situ prepared copper amide in refluxing pyridine. Cyclic voltamm ograms of meta-connected derivatives consisted of irreversible waves w hich imply side reactions in addition to oxidation to aminium radical- cations.