CHIRAL RECOGNITION IN THE ELECTRON-TRANSFER REACTION BETWEEN OPTICALLY-ACTIVE SCHIFF-BASE-OXOVANADIUM(IV) AND SCHIFF-BASE-OXOVANADIUM(V) COMPLEXES

Authors
NAKAJIMA K ANDO Y INAMO M KOJIMA M
Citation
K. Nakajima et al., CHIRAL RECOGNITION IN THE ELECTRON-TRANSFER REACTION BETWEEN OPTICALLY-ACTIVE SCHIFF-BASE-OXOVANADIUM(IV) AND SCHIFF-BASE-OXOVANADIUM(V) COMPLEXES, Chemistry Letters, (11), 1995, pp. 1017-1018
Citations number
7
Categorie Soggetti
Chemistry
Journal title
Chemistry Letters → ACNP
ISSN journal
03667022
Issue
11
Year of publication
1995
Pages
1017 - 1018
Database
ISI
SICI code
0366-7022(1995):11<1017:CRITER>2.0.ZU;2-9
Abstract
The kinetics of the electron-transfer reaction between [VO{3-MeOsal-(R R) or (SS)-chxn}] and [VO{sal-(RR)-chxn}](+) were studied using the st opped flow method in acetonitrile over the temperature range of 5 - 25 degrees C. The reactions were enantioselective. The ratio of the rate constant of the electron-transfer between [VO{3-MeOsal-(SS)-chxn}] an d [VO{sal-(RR)-chxn}](+) (k(SS-RR)) and that between [VO{3-MeOsal-(RR) -chxn}] and [VO{sal-(RR)-chxn}](+) (k(RR-RR)) was 2.0 (k(SS-RR)/k(RR-R R)) at 25 degrees C.