ESR OF THE PI-RADICAL FORMED BY PHOTOREDUCTION OF BIS(1,2,5-SELENADIAZOLO)-TETRACYANOQUINODIMETHANE IN METHANOL - OBSERVATION OF A LARGE SE-77 HFS

Authors
HIRAYAMA M TERASAKA T MORITA Y SUZUKI T YAMASHITA Y MIYASHI T
Citation
M. Hirayama et al., ESR OF THE PI-RADICAL FORMED BY PHOTOREDUCTION OF BIS(1,2,5-SELENADIAZOLO)-TETRACYANOQUINODIMETHANE IN METHANOL - OBSERVATION OF A LARGE SE-77 HFS, Chemistry Letters, (11), 1995, pp. 1021-1022
Citations number
11
Categorie Soggetti
Chemistry
Journal title
Chemistry Letters → ACNP
ISSN journal
03667022
Issue
11
Year of publication
1995
Pages
1021 - 1022
Database
ISI
SICI code
0366-7022(1995):11<1021:EOTPFB>2.0.ZU;2-U
Abstract
A large Se-77 hfs was observed in the ESR spectrum of a radical genera ted by photoreduction of the electron acceptor, BSDA-TCNQ(3), with 355 nm laser irradiation in methanol. This spectrum was identified as the anion radical of a proton adduct of 3, which was supported by the MO calculation.