SOLUBLE POLYIMIDES BASED ON DIANHYDRIDE O F ,4-DICARBOXYPHENOXY)PHENYL]-1,1,1,3,3,3-HEXAFLUORO PROPANE

Authors
MATVELASHVILI GS RUSANOV AL VLASOV VM KAZAKOVA GV ROGOZHNIKOVA OY
Citation
Gs. Matvelashvili et al., SOLUBLE POLYIMIDES BASED ON DIANHYDRIDE O F ,4-DICARBOXYPHENOXY)PHENYL]-1,1,1,3,3,3-HEXAFLUORO PROPANE, Vysokomolekularnye soedinenia. Seria A, 37(11), 1995, pp. 1941-1944
Citations number
20
Categorie Soggetti
Polymer Sciences
Journal title
Vysokomolekularnye soedinenia. Seria A → ACNP
ISSN journal
05075475
Volume
37
Issue
11
Year of publication
1995
Pages
1941 - 1944
Database
ISI
SICI code
0507-5475(1995)37:11<1941:SPBODO>2.0.ZU;2-L
Abstract
The reaction of disodium salt of 2,2-bis(4-oxyphenyl)-1,1,1,3,3,3-hexa fluoropropane with a two-fo Id molar amount of 4-nitro-N-methylphthali mide under the conditions ensuring aromatic nucleophilic nitro-substit ution produced imido-4-oxy)phenyl]-1,1,1,3,3,3-hexafluoropropane. Its hydrolysis and subsequent dehydration yielded dianhydride of the corre sponding tetracarboxylic acid. Polycondensation of this dianhydride wi th mono-, di-, tri, or tetraphenyl aromatic diamines in m-cresol produ ced soluble aromatic polyimides with low melt viscosity.