STRUCTURAL INVESTIGATION OF A TETRAZENE D ERIVATIVE - APPLICATION TO THE DETERMINATION OF CIS-TRANS CONFIGURATIONS OF N,N'-AZO-3-AZABICYCLO[3,3,0]OCTANE

Authors
DELALU H ELKHATIB M MARCHAND A MENTZEN BF
Citation
H. Delalu et al., STRUCTURAL INVESTIGATION OF A TETRAZENE D ERIVATIVE - APPLICATION TO THE DETERMINATION OF CIS-TRANS CONFIGURATIONS OF N,N'-AZO-3-AZABICYCLO[3,3,0]OCTANE, Comptes rendus de l'Academie des sciences. Serie II. Mecanique, physique, chimie, astronomie, 321(10), 1995, pp. 431-436
Citations number
6
Categorie Soggetti
Multidisciplinary Sciences
Journal title
Comptes rendus de l'Academie des sciences. Serie II. Mecanique, physique, chimie, astronomie → ACNP
ISSN journal
12518069
Volume
321
Issue
10
Year of publication
1995
Pages
431 - 436
Database
ISI
SICI code
1251-8069(1995)321:10<431:SIOATD>2.0.ZU;2-6
Abstract
A structural investigation by X-ray diffraction on a tetrazene derivat ive, the N, N'-azo-3-azabicyclo[3, 3, 0]octane, shows that this compou nd crystallizes in the triclinic system with space group P (1) over ba r. The unit-cell corresponds to a centro-symmetrical C14H24N4 formula unit, the volume of which is 351.1 Angstrom(3). Data processing by dir ect methods reveals that the geometry of the molecule presents a cis c onfiguration for the bicyclic bridgelink and a trans one for the azo g roup.